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TRANSPARENT SPINEL CERAMICS
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Spinel Capabilities Overview
Dr. Larry Fehrenbacher interviewed by General Norman Schwarzkopf on World Business Review
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Transparent magnesium aluminate ceramics have been in existence for many decades. However, at few times in history has spinel been available as a commercial product and until now, there has not been as large an interest or effort to make transparent polycrystalline spinel a marketable reality. Due to the ever-increasing performance demands of current and next-generation electro-optic platforms, transparent magnesium aluminate spinel is suitable in more applications because of its extended transparency in the mid-wave IR (MWIR). Spinel is also emerging as a transparent armor solution for tactical and combat vehicles against escalating threats. Furthermore, as a simple ceramic oxide, its processability affords economy of scale that makes it attractive for meeting the ever demanding cost targets of advanced weapons systems and commercial products.
Technology Assessment & Transfer Inc. (TA&T), is leading the effort in the United States to develop and commercialize transparent polycrystalline spinel ceramics to meet these future needs. Current development efforts have benefited by on-going and previous support from the Army, Navy, and Air Force as well as the Missile Defense Agency and Department of Energy.
Spinel (MgAl2O4) Optical Ceramic is a transparent polycrystalline ceramic whose combination of high hardness, light weight and broadband optical properties make it a leading candidate for stringent optical applications and transparent armor. Its transmission range spans the range from 0.19 um to 6.0 um and exceeds that of sapphire and ALON™
Spinel Optical Components are fabricated using proprietary processing methods in a wide variety of sizes up to 18” in diameter and 14” x 16” windows. Detailed quotes can be provided on request for specific components by contacting the TA&T Optical Ceramics Division, 215 Najoles Rd., Millersville MD 21108; Attn: Mr. Cliff Parsons, 410-987-1656 phone.
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TYPICAL PROPERTIES |
| Composition |
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MgAl2O4 |
| Grain Size |
. . . . . . . . . . |
100-200 microns |
| Structure |
. . . . . . . . . . |
Cubic, Spinel, Isotropic |
| Density |
. . . . . . . . . . |
3.58 g/cc |
| Form |
. . . . . . . . . . |
polycrystalline |
| Melting Point |
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2135 °C |
| Young's Modulus |
. . . . . . . . . . |
277 GPa |
| Shear Modulus |
. . . . . . . . . . |
192 GPa |
| Poisson's Ratio |
. . . . . . . . . . |
0.26 |
| Hardness |
. . . . . . . . . . |
1645 Kg/mm
(Knoop Indentation, 200 g load) |
| Fracture Toughness |
. . . . . . . . . . |
1.5-2MPa-m1/2 |
| Flexure Strength |
. . . . . . . . . . |
185-250 GPa |
| Specific Heat |
. . . . . . . . . . |
0.21 cal/g-°C |
| Thermal Conductivity |
. . . . . . . . . . |
14.7 W/moK @25 °C |
| Coeff. Ther.Expansion |
. . . . . . . . . . |
25-100 °C - 6.09x10-6
25-500 °C - 7.30x10-6
25-1000 °C - 7.90x10-6 |
| Thermal Shock |
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| Parameter R' |
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1.39 vs. ALON™ 1.2* (Higher is Better) |
| Wavefront Error Potential |
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¼ wave over 11" aperture at 0.5" thickness |
* Gentilman , R.L. "Infrared and Optical Transmitting Materials" SPIE Vol. 683, 1986 |
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